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Phosphate concentration and pH in boiler water treated with

Boiler Water - an overview | ScienceDirect Topics

Boiler water treatment has basically two phases: First, we remove impurities from the water to the desired cleanliness. Second, we add chemicals to the feedwater to adjust the pH, create less favorable conditions for deposition, and remove oxygen. Special water treatment chemicals are used in almost all boilers.

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Questions And Answers Phosphate Hideout

increases. The severity of phosphate hideout is boiler, heat flux, temperature, pressure, and boiler cleanliness specific. Phosphate Hideout In simple terms we dose phosphate to control boiler water hardness or in case of sea water tube leakage or to control Ph… dosing too high a concentration of phosphate results in phosphate

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Boiler Water Treatment Chemicals, Feed, and Control

Boilers 170 Boiler Water Treatment Chemicals, Feed, and Control - Perhaps It Is More Complicated Than Phosphate treatment would be easier to control with variations in feedwater hardness. the boiler polymer concentration would have increased to over 200 ppm. Upon high fire when production resumes,

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5-2 Recovery Boiler Water Treatment - TAPPI

Phosphate Effect on Boiler Water pH Sodium-To-Phosphate Molar Ratio Blowdown Phosphate, mg/L p H NaOH TSP DSP (MSP) 3 . 0 2 . 6 2 . 4 2. 2 . 1 2 . 0 Summary: What Should You Know? 6Top Chemistry Parameters in Steam/Water Cycle ¾Conductivity µS/cm ¾pH ¾Dissolved Oxygen, ppb O 2 (and Oxygen Scavengers) ¾Hardness, ppm CaCO 3 ¾Phosphate, ppm PO 4

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Phosphate concentration and pH in boiler water …

(PDF) Using of congruent phosphate as equilibrium

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Control of Sodium to Phosphate Ratio in Real Time in a

Apr 25, 1999 · Some supercritical and once through boilers are treated by all-volatile means (hydrazine plus ammonia) or oxygenated treatment. The coordinated phosphate approach is to maintain a chemistry in the bulk boiler water. The chemistry is to maintain a septic sodium to phosphate molar ratio so as to prevent extremes of pH from developing under

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Boiler system pH/phosphate program control method - NALCO

Aug 22, 1994 · The above descriptions of boiler systems, pH/phosphate programs and other treatment additives for boilers are not exhaustive, and further descriptions are available in the literature in the boiler field, including in "The Chemical Treatment Of Boiler Water", James W. McCoy, pages 65-68, 81-87 and 131-139, 1981, 2nd printing 1984, Chemical

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(PDF) Using of congruent phosphate as equilibrium

The concentration of phosphate in boilers water is dependent on drum pressure and water quality, a typical high pressure boiler fed with de-mineralized water would tend to run with low concentration of 1 to 5 mg/l range, while a lower pressure boiler running with softened water might go to 25 mg/l.

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Phosphate Continuum (PC) - What Products Do You Need

The minimum boiler water pH is 9.0 regardless of program type. The minimum phosphate is 0.2 mg/L. PC (L) or Phosphate Continuum (Low) requires higher purity feedwater, but uses lower phosphate target ranges and minimizes the propensity for phosphate hideout. PC (H) or Phosphate Continuum (High) is the most forgiving program if there are upsets

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Using of congruent phosphate as equilibrium phosphate

The relation between pH of boiler water and phosphate residue concentration is shown in fig. 2. This curve is very close to the typical tri-sodium phosphate concentration in fig. 1. The low pH values of boiler water compared to phosphate residue concentration can be attributed to two factors, first, di-sodium phosphate formed

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(PDF) Using of congruent phosphate as equilibrium

The concentration of phosphate in boilers water is dependent on drum pressure and water quality, a typical high pressure boiler fed with de-mineralized water would tend to run with low concentration of 1 to 5 mg/l range, while a lower pressure boiler running with softened water might go to 25 mg/l.

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BOILER WATER TREATMENT AND CONDENSATE RETURN …

fed to the boiler feed water, or to the storage space of the deairating heater. These then are the three basic chemicals used in internal boiler water treatment; phospate, caustic soda, and sodium sulfite. There is no mystery about what they do, or how they work. Most often these are the only chemicals required for clean boilers, year after year.

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Questions And Answers Phosphate Hideout

increases. The severity of phosphate hideout is boiler, heat flux, temperature, pressure, and boiler cleanliness specific. Phosphate Hideout In simple terms we dose phosphate to control boiler water hardness or in case of sea water tube leakage or to control Ph… dosing too high a concentration of phosphate results in phosphate

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Phosphate Hideout

When using phosphate boiler water treatment, the concentration of phosphate should not exceed the equilibrium concentration.This is the maximum concentration of PO4 in the boiler water that the boiler can tolerate under the highest heat flux conditions (full load).

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Boiler Water Treatment Part 2 – Internal Treatment

Best Practice in Boiler Water Treatment Boiler Water Treatment Part 2 – Internal Treatment Generally it is desirable to have a slightly high pH for boiler feed water. Ideally the feed water should be in the range of pH 8.5 – 9.5. Phosphate: 30 – 60mg/kg PO . 4 .

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Boiler Water Treatment - Association of Water Technologies

• The pH of the feed water should be below 9.2, to prevent copper loss in the system • Optimum pH in the feed water should be 8.5-9.2 Deaerator Ratings • Deaerators are categorized by the quantity of oxygen that they are able to remove at boiling point. The categories are; –Preheat Boiler Feed (Atmospheric Feed Water Tank)

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Boiler Water Phosphate Injection

1995/12/1 · Only drum boiler units using phosphate boiler water treatment are included in this study. Information on concentration and transport of chemical impurities and sodium phosphate around drum boiler cycles was collected and correlated with chemical composition of low pressure (LP) turbine deposits collected after the water and steam

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Boiler Water Chemical - Robinson India

Boiler Water Chemicals. As well as being a service company Robinson India manufactures and supplies a range of high-quality boiler water treatment chemicals all over India and export customers. Our chemicals are suitable for land, marine & heritage water boilers. A badly treated steam boiler is a potential bomb, so getting the feed water

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Boiler Water Phosphate Injection

1995/12/1 · Only drum boiler units using phosphate boiler water treatment are included in this study. Information on concentration and transport of chemical impurities and sodium phosphate around drum boiler cycles was collected and correlated with chemical composition of low pressure (LP) turbine deposits collected after the water and steam

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Water Handbook - Preboiler & Industrial Boiler Corrosion

In high-purity systems, raw water in-leakage (e.g., condenser leakage) lowers boiler water pH when magnesium hydroxide precipitates, resulting in corrosion, formation of atomic hydrogen, and initiation of hydrogen attack. Coordinated phosphate/pH control can be used to minimize the decrease in boiler water pH that results from condenser leakage.

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Control of Sodium to Phosphate Ratio in Real Time in a

Apr 25, 1999 · Some supercritical and once through boilers are treated by all-volatile means (hydrazine plus ammonia) or oxygenated treatment. The coordinated phosphate approach is to maintain a chemistry in the bulk boiler water. The chemistry is to maintain a septic sodium to phosphate molar ratio so as to prevent extremes of pH from developing under

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pH Treatment - CleanBoiler.org

Therefore, adequate disodium phosphate must be available to combine with all of the free caustic in order to form trisodium phosphate. A slightly basic pH should be maintained in the boiler feedwater system. ASME suggests feed water to be kept at a pH of 8.3-10.5. Sodium phosphates help fulfill this requirement.

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Chemical Treatment Requirements for Steam and Hot Water

Jun 12, 2017 · Sodium hydroxide, disodium phosphate and trisodium phosphate are utilized to control and adjust the pH of the boiler water along the equilibrium curve. Disodium phosphate, being more acidic, depresses the boiler pH. Trisodium phosphate reacts in the boiler to produce caustic alkalinity and raise the pH.

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Phosphate Hideout

Phosphate Hideout. When the concentration of phosphate in the boiler water is too high, phosphate will react with boiler scale forming iron and iron sodium phosphates or precipitate to form a solid phase on the hot boiler tube surfaces and elsewhere. This phenomenon is called phosphate hideout and it can result in changes of pH, as well as the

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Ph And Phosphate Concentration In Bfw And Steam Drum

May 02, 2000 · tied up by dispersants and chelants and remain suspended in the boiler water where they can be removed by continuous surface or bottom blow down. Left improperly treated silica and iron both can form harmful deposits. ASME Phosphate Treatment Guidelines (boilers below 600 PSIG) OH-Alkalinity 100-600ppm Phosphate 30-50ppm Silica 200 - (0.25x Boiler …

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Water Treatment for Steam Boiler Applications

Nov 10, 2014 · A properly exercised water treatment program for steam boiler applications is essential to satisfy three main objectives: continuous heat exchange, production of high quality steam, and corrosion/deposition protection. A water treatment program consists of both external and internal treatment where preventative measures are achieved through mechanical and …

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Phosphate Polymer Treatment for Steam Boilers

Accepta 2347 is a blended liquid treatment of polymers and is an ideal treatment for steam boilers using softened make-up water. Accepta 2347 is effective against iron and phosphate sludges. The organic polymer provides transport of the calcium, magnesium, iron, phosphate and silica through the boiler.

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BOILER WATER TREATMENT FOR KILN DRY OPERATIONS …

hydroxide. If insufficient boiler water alkalinity is being maintained, magnesium can combine with phosphate. Magnesium phosphate has a surface charge that can cause it to adhere to tube surfaces and then collect other solids. For this reason, alkalinity is an important part of a phosphate precipitation program. Phosphate Treatment Alone Not

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Co-ordinated And Congruent Phosphate Treatment Of Boiler Water

Falling into the area on the co-ordinated phosphate pH diagram below the lower dotted line means that normal treatment to bring back into the target area is impossible. The only way of recovering the situation is by blowing large quantities of water out of the boiler The ideal time for this is during trip testing when the boiler is isolated

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Uses & Applications of Phosphates in Cooling Water Treatment

3. Low water treatment costs are necessary. Boiler Feedwater A key to protecting the boiler system is to treat the boiler feedwater entering the system. Boiler feedwater can be protected from corrosive conditions through coordinated phosphate/pH control treatment. Phosphate buffers the boiler water, reducing the chance of large pH swings

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Boiler Water Phosphate Injection

1995/12/1 · Only drum boiler units using phosphate boiler water treatment are included in this study. Information on concentration and transport of chemical impurities and sodium phosphate around drum boiler cycles was collected and correlated with chemical composition of low pressure (LP) turbine deposits collected after the water and steam

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What is the purpose of phosphate in boiler water?

Phosphate concentration and pH in boiler water treated with congruent phosphate. Source publication Using of congruent phosphate as equilibrium phosphate boilers water treatment Conference Paper

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Inferred pH in Steam Plant Water Chemistry Monitoring

Solid treatment chemicals are fed only to boiler water, never to condensate and feedwater. Common boiler water treatment chemicals are sodium hydroxide and sodium phosphate salts. They are used to adjust boiler water pH to reduce corrosion and buffer the water against acid-forming contaminants. Boiler water chemicals by and large remain in the

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Successful Caustic Treatment Of Electric Utility Drum Boilers

Mar 22, 2009 · The high boiler water pH also protected boiler surfaces from corrosion. Current Phosphate Treatment Concepts Once acid phosphate corrosion was identified, the use of Congruent Phosphate Treatment (CPT) in high pressure boilers was greatly reduced. Equilibrium Phosphate Treatment (EPT) replaced CPT in many cases.

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Plant Service Bulletin: Boiler Water Phosphate Chemistry

Phosphate anti-scaling treatment is to add phosphate solution to keep a certain amount of phosphate radical in the boiler water. Therefore, the calcium ions in the boiler water will react with phosphate radical, the resulting basic calcium …

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Phosphate Hideout

When using phosphate boiler water treatment, the concentration of phosphate should not exceed the equilibrium concentration.This is the maximum concentration of PO4 in the boiler water that the boiler can tolerate under the highest heat flux conditions (full load).

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The International Association for the Properties of Water

Makeup Water MU Water which is added to compensate for losses of water and steam from the system Mono-sodium phosphate MSP NaH2PO4 Once-through boiler or HRSG Benson Boiler Boiler in which output steam is generated from input water by complete evaporation. There is no recirculation of boiler water. Oxygenated Treatment OT Combined Water

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Successful Caustic Treatment Of Electric Utility Drum Boilers

Mar 22, 2009 · The high boiler water pH also protected boiler surfaces from corrosion. Current Phosphate Treatment Concepts Once acid phosphate corrosion was identified, the use of Congruent Phosphate Treatment (CPT) in high pressure boilers was greatly reduced. Equilibrium Phosphate Treatment (EPT) replaced CPT in many cases.

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(PDF) Using of congruent phosphate as equilibrium

Figure 4: Phosphate concentration and pH in boiler water treated with congruent phosphate. The congruen t phosphate salts in this situation is used and working in the

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Considerations for High Pressure Boiler Chemical Treatment

acidic phosphate attack. When the boiler pH and phosphate levels stay within the control boundaries, the boiler water should be non-corrosive. The vector diagram indicates the direction a point will go on the phosphate-pH diagram if a certain chemical is added to the system. Also shown is the affect of increased continuous blowdown.

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